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Emerald

The timeless appeal of emerald can be summed up in three words written in the year 50 AD: “Nothing greens greener.” Roman historian Pliny the Elder was explaining the desire for the supreme green gem not only in Rome but throughout the ancient world.

Cleopatra, Egypt’s tempestuous female monarch, was as famous for wearing emeralds in her time as Liz Taylor, the actress who played her in a 1969 movie, is for wearing diamonds in ours. Mummies in ancient Egypt were often buried with an emerald on their necks carved with the symbol for verdure, flourishing greenness, to symbolize eternal youth.

Islamic texts describe the Garden of Paradise as carpeted with emerald. The Moguls of India, including Shah Jahan, the builder of the Taj Mahal, loved emeralds so much they inscribed them with sacred text and wore them as talismans. Some of these sacred stones, called Mogul Emeralds, can still be seen in museums and collections today.

emerald , coscuez mine. columbia

The Incas had an emerald goddess, a fabulous emerald the size of an ostrich egg. In tribute they sacrificed her children: smaller emeralds that were presented to the goddess.

Because the rich green colour of emerald is the colour of spring, it has long symbolized love and rebirth. As the gem of Venus, it was also considered an aid to fertility.

The Incas had an emerald goddess, a fabulous emerald the size of an ostrich egg. In tribute they sacrificed her children: smaller emeralds that were presented to the goddess.

Because the rich green colour of emerald is the colour of spring, it has long symbolized love and rebirth. As the gem of Venus, it was also considered an aid to fertility.

The emeralds the ancients adored, from mines in Egypt and perhaps what is now Afghanistan, were nowhere near as beautiful as those mined today. The modern emerald bounty began almost five centuries ago when Spanish explorers arrived in the new world. Montezuma presented Cortes with a staggering emerald crystal much larger and finer than any ever seen before.

The Spaniards spent years searching for the source of the fantastic green gems. They found it finally in what is today Colombia. In our century, several more emerald El Dorados have been discovered. While Colombia is still the world’s largest and most famous emerald-producing country, Brazil and Zambia have emerged as major sources for this gem. As could be expected, emeralds from each of these countries possess their own distinctive characteristics. If you are buying mainly or solely for colour, Colombian stones have the highest reputation. However, the finest Brazilian stones rival those of Colombia for colour. If clarity is your primary concern, Zambian stones are renowned for their crystalline appearance and have a rich, robust green to boot.

Emerald is most often cut in a rectangular step-cut, which is now popularly known as the emerald cut. Smaller sizes are also found in rounds, ovals, pear shapes and marquise cuts. You may have to look a while for an unusual shape in a larger size. Due to their rich colour, emeralds are also spectacular when cut in a smooth-domed cabochon cut.

Emeralds, among the rarest of gems, are almost always found with birthmarks, known as inclusions. S some inclusions are expected and do not detract from the value of the stone as much as with other gemstones. However, you should look to make sure that fissures do not go too deep into the stone so that it might be weakened enough to break if it were hit accidentally. The fissures that are characteristic of emerald are traditionally filled with oil or resin to make them less visible to the eye. You should assume that your emerald has been improved in this way unless it has a laboratory certificate indicating otherwise: such rare stones command a considerable premium.

Gemmologists can detect the presence of fillers when a stone is examined under a microscope. But it’s nearly impossible to identify the agent without the aid of very expensive equipment that only a handful of labs in the world can afford. For this reason, most gem labs note that an emerald has been enhanced, but can’t say with what medium.

Nevertheless, the trade generally divides enhancement agents into two categories: natural and man-made. Understandably, many dealers dislike the idea of using a man-made substance to beautify a natural gem. Since emeralds have such a long and rich tradition of connoisseurship, these dealers feel that only traditional substances should be used: natural oils and resins such as Canada balsam or cedar wood oil. However, these natural oils, over time, dehydrate or leak out. That’s why most in the trade now rely on longer-lasting man-made substances like epoxy resins for emerald face lifts. No matter which substance is used, the end result is the same: less obvious inclusions, and more life in your emerald.

Avoid cleaning emerald with hot soapy water or steam and never clean an emerald in an ultrasonic cleaner because the oil or resin could be removed or damaged, making fissures more visible. Emeralds are durable gemstones with a hardness of 7.5 to 8. However, emeralds with many inclusions should be treated with some care and be protected from blows.

Clean emerald with mild dish soap: use a toothbrush to scrub behind the stone where dust can collect.

The Emerald Family – Beryl – click here for more information

Emerald Image Page ; click here

Emeralds – their chemical composition and structure
Emeralds belong to the group of minerals called beryl, which belong to a broader class of minerals called silicates, the most abundant class of minerals found on the surface of the earth. Beryl belong to a sub-class of silicates known as Cyclosilicates, in which six tetrahedral silicate ions (SiO4))‾ are linked together to form a hexagonal shaped ring, whose symmetry is reflected in the final crystal form, which are hexagonal shaped crystals. As the six (SiO4)‾ ions link together one oxygen atom is eliminated resulting in the structure [(SiO3)6]‾. The negative charges on the rings are balanced by the positive charges on the metal ions of aluminum (Al3+) and beryllium (Be3+), which hold the rings together in the crystal structure. The overall chemical formula of beryl is Be3Al2(SiO3)6, which is known as Beryllium Aluminum Silicate. Two other minerals that have a similar structure to beryl, but different chemical composition are tourmaline and cordierite.

What causes the green color of emerald ?

 

Pure beryl is colorless and known as Goshenite. The presence of trace quantities of the atoms of a transition element in the crystal structure can induce different colors to beryl, producing its different varieties, such as emeralds (chromium/vanadium-green), aquamarine (iron-light blue), morganite (manganese-pink), heliodor (iron/uranium-greenish-yellow/  golden)) and green beryl (vanadium-pale-green), bixbite (manganese-red), golden-beryl (uranium-golden/yellow). In emeralds the brilliant “emerald-green” color is produced by traces of chromium and/or vanadium atoms associated with the crystal. Some believe that the deep-green color of emerald is actually caused by chromium. The pale-green colors caused by vanadium, is simply known as green beryl.

The deep-green color is the best known variety of emerald, but emeralds also have various other shades of green. The world renowned emerald mines of Colombia produces different tones of green, which are almost characteristic of the mine in which they are found. The emeralds produced in the Muzo emerald mines are a deep herbal-green color, and those produced in the Coscuez and Penas Bancas mines are a typical yellowish-green color. Emeralds of the Chivor mines are bluish-green in color, and those of the Gachala mines are pale-green in color. The color of an emerald is of paramount importance in deciding its value. Generally, the deeper and more vivid the green color the more valuable is the emerald, but stones that are too light or too dark in color are generally less valuable. The top colors in emeralds are the deep vivid-green, the slightly bluish-green and the slightly yellowish-green colors. All these favorable colors are produced in the emerald mines of Colombia and hence the premier source of top-quality emeralds in the world is Colombia.

 

Presence of inclusions – jardin – is a characteristic feature of emeralds

The presence of flaws and inclusions is a hallmark of most natural emeralds, and unfortunately the best colored stones are sometimes the most included. The types of flaws found are cracks and fissures and the inclusions can be solid, liquid and gaseous. The Colombian emeralds originating from the Muzo and Chivor mines  have the typical three-phase inclusions containing gas, fluid and crystals of halite. Muzo emeralds also contain calcite and yellow-brown needles of the mineral parisite. In the Chivor emeralds the characteristic inclusions are pyrite and albite. The Zimbabwean emeralds have inclusions of acicular tremolite. The Zambian emeralds have tourmaline and biotite inclusions.

The presence of flaws and inclusions in emeralds is probably a symbol of its turbulent genesis. The flaws seem to have been produced due to the tension involved in creating the necessary geological conditions conducive to their formation. Gem beryl is almost found exclusively in hydrothermal veins, pegmatites, and at the contact zones of large igneous intrusions that invade aluminous schist, shale or impure limestone. Beryllium is provided by the volatile fraction of the vein liquid or magma, and aluminum is provided by the host rock. The turbulent genesis of the emerald impedes the undisturbed formation of large flawless crystals. Thus it is extremely rare to have a large emerald with good color, clarity and transparency. If it occurs, it is an exception rather than the general rule. Gemologists refer to the inclusions, cracks and fissures commonly found in emeralds as “Jardin” which in the French language means “Garden.” In other words the inclusions are compared metaphorically to tender little green plants in the pure green emerald garden. Emeralds had been held in high esteem and regard and highly valued since ancient times, in spite of their inclusions. In fact the presence of inclusions in natural emeralds confirms the authenticity of the gemstone. Synthetic emeralds too have inclusions but they are fewer and entirely different in nature.

In spite of their inclusions emeralds rank among the five elite gemstones in the world, which are diamond, ruby, emerald, sapphire and pearls. Due to their extreme rarity the price of a top-quality emerald may sometimes be higher than that of a diamond of the same weight.

Why the emerald-cut was developed for emeralds ?

The presence of inclusions in emeralds have imparted some disadvantages to the gemstone. The hardness of emeralds is 7.5 to 8.0 on the Mohs scale, which is quite high, but in spite of its hardness, the toughness of emerald is low. This is because the presence of inclusions have made emeralds somewhat brittle. Again for the same reason cutting of emeralds is a very difficult task even for the most skilled gem-cutter, and presents a special challenge, not only because of the high value of the raw crystals, but also because of the frequent flaws and inclusions. The emerald-cut which is a rectangular or square shaped step-cut with beveled corners was specially developed by gem cutters not only to bring out the intrinsic beauty of the gemstone, but also to protect it from mechanical strain. While emeralds are also cut in other classical shapes, if the stone is heavily included, it is usually cut as a rounded cabochon.

Oil treatment of emeralds an accepted trade practice

Natural emeralds are treated with oils, a form of treatment generally accepted in the trade. Oil treatment fills the cracks and cavities in the stone. If the oil used has a refractive index very close to that of the emerald the cracks and fissures become invisible. Some of the traditional oils that had been used for this purpose are Canada balsam and cedar wood oil, but several other crack filling substances have been developed for this purpose. It is because of this treatment that an ultrasonic bath cannot be used for cleaning emeralds, and it is advised that one should remove his or her emerald rings before handling soaps and detergents. In any case oil treatment is not permanent, and can decrepitate with time or form “sweats” in strong sunlight.

Some physical and optical properties of emeralds

Emeralds crystallize in the hexagonal crystal system, giving rise to well formed hexagonal prisms. The hardness of emerald is 7.5 to 8.0 on the Mohs scale. This hardness is sufficient not to cause scratches on emeralds set in jewelry, but the toughness of the gemstone is quite low, because of the presence of inclusions. The specific gravity of emerald is quite low and varies between 2.67 to 2.78. The refractive index is also quite low, varying between 1.565 and 1.599. The refractive index seem to vary with the place of origin of the emerald.

The birefringence is low varying between 0.005 and 0.009, and so is the dispersion equal to 0.014. The low dispersion and refractive index reduces the fire and brilliance of the stone, but this is somewhat compensated by the vitreous luster of the stone, its deep-green color, transparency and the emerald-cut of the stone which seems to increase its dispersion. Some emeralds are opaque and may not be of gem-quality. The Mughal Emerald, which is the subject of this web page is actually an opaque emerald, which is more suitable for carving than to be used as a gemstone. Dichroism in emeralds is quite distinct, changing from blue-green to yellow-green. Natural emeralds do not fluoresce in ultra-violet light, but synthetic emeralds may show a dull-red fluorescence. The low specific gravity, and refractive index combined with the distinct dichroism and the lack of fluorescence in u-v light are the distinguishing properties of natural emeralds. Synthetic emeralds also have a slightly lower refractive index and specific gravity than the natural emeralds.

 

Vanadium: the secret behind Muzo emerald perfect color

November 14, 2010

 

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Emerald deposits in Muzo have a strongly characterized chemical composition, featuring a high vanadium content in particular.
While vanadium is found in several emerald deposits, its quantity in Muzo emeralds is remarkable.
An X-ray fluorescence analysis on a very beautiful Muzo emerald shows here a higher percentage of vanadium than of chromium, the common coloring element in emeralds.
This spectacular proportion of vanadium (≈0.5% of the stone), associated with a very low iron content, is obviously a key component in the exceptional color of gems from this historical mining site.